Reef Chemistry Question of the Day #301: Refractometers

[Randy Holmes-Farley]

Reef Chemistry Question of the Day 301

Which of the following is a refractometer measuring to determine seawater salinity?

1. Changes in the wavelength of light passing through the sample
2. Changes in the speed of light passing through the sample
3. Changes in the intensity of light passing through the sample
4. Changes in the frequency of light passing through the sample

Good luck!

Previous Reef Chemistry question of the day:

Reef Chemistry Question of the Day# 300: Specific Gravity

Reef Chemistry Question of the Day 300 Which of the following has the highest specific gravity? A. Normal seawater (35 ppt) B. Kalkwasser/limewater (saturated calcium hydroxide) C. Vodka for dosing (80 proof) D. Vinegar for dosing (5% acidity) Good luck! Previous Reef Chemistry Question of...

www.reef2reef.com

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[Tahiti]

This is a great question that I did not know the answer to! Had to google it so I would say #1.

 

[tzabor10]

1 no google

 

[Cajun86]

1 of course

 

[Salty_Northerner]

I'm thinking 1 myself. 2 made me lol (speed of light 186000 mps is pretty high tech refractometer

 

[TehBrainz]

1. Refraction afterall

 

[Sophie"s mom]

Reef Chemistry Question of the Day 301

Which of the following is a refractometer measuring to determine seawater salinity?

1. Changes in the wavelength of light passing through the sample
2. Changes in the speed of light passing through the sample
3. Changes in the intensity of light passing through the sample
4. Changes in the frequency of light passing through the sample

Good luck!

Previous Reef Chemistry question of the day:

Reef Chemistry Question of the Day# 300: Specific Gravity

Reef Chemistry Question of the Day 300 Which of the following has the highest specific gravity? A. Normal seawater (35 ppt) B. Kalkwasser/limewater (saturated calcium hydroxide) C. Vodka for dosing (80 proof) D. Vinegar for dosing (5% acidity) Good luck! Previous Reef Chemistry Question of...

www.reef2reef.com

.

Using process of elimination, I come up up with #1. But it is a total guess based on what simply sounds right to me.

 

[Alexraptor]

Definitely Number #2.
I actually paid attention during physics and remember well that refraction is the result of the speed of light changing when transitioning from one medium to another.

And I think now is also a good time to point out that the light speed constant c, is the speed of light through a vacuum only.

 

[SPS2020]

None of the above; it's the flavor.

 

[lil sumpin]

I always feels like pirate pointing it up at the light

 

[jbrady429]

#2 changes in speed of light through the sample.

 

[Bob Kukura]

2

 

[Pod_01]

I say 2…

 

[KrisReef]

I thought it were the angle change that the light were traveling down as it passes through the liquid. I know for sure that it doesn't slow down unless the pH is too low, or unless you are measuring with a swing arm, then it might?

 

[bureau13]

I feel it's gotta be 2 because 1 and 4 are two ways of looking at the same thing, and I don't think it has anything to do with intensity. If it weren't for that intensity bit at #3 I would be tempted to say all of the above.

 

[GlassMunky]

Definitely Number #2.
I actually paid attention during physics and remember well that refraction is the result of the speed of light changing when transitioning from one medium to another.

And I think now is also a good time to point out that the light speed constant c, is the speed of light through a vacuum only.

since we re talking about the speed of light through mediums..... this always makes me smile

 

[KStatefan]

My guess is #2

 

[Johnd651]

I wish I had seen these before... like the other 300 days.

2

Change in refractive index=speed of light/speed of light of sw

 

[Randy Holmes-Farley]

And the answer is:

Which of the following is a refractometer measuring to determine seawater salinity?

1. Changes in the wavelength of light passing through the sample
2. Changes in the speed of light passing through the sample
3. Changes in the intensity of light passing through the sample
4. Changes in the frequency of light passing through the sample

Refractometers and Salinity Measurement - REEFEDITION

Title photo by R2R member Rskillz By Randy Holmes-Farley Salinity is one of the most important parameters measured in reef aquaria. It controls not only the salt balance between an organism and its surrounding environment, but also the levels of a host of ions Read more here...

www.reefedition.com

What is the Index of Refraction?

The index of refraction (or refractive index) is the ratio of the speed of light traveling through a vacuum to the speed of light in the material being tested. Most aquarists do not realize that when using a refractometer, they are measuring the speed of light through their aquarium’s water, so having such knowledge might be a good way to impress friends with your technical abilities!

Light travels through most materials more slowly than it does through a vacuum, so their refractive index is higher than 1.00000. The detailed mathematics and physics behind refractive index are actually quite complicated, because it is often a complex number with real and imaginary parts, but a simple version is adequate for all purposes that a reef aquarist would encounter. Some materials slow light traveling through them more than others, and slower light travel leads to a higher refractive index. Table 1 shows some typical refractive index values for comparative purposes.

In solutions of two compounds, such as ethyl alcohol in water, sugar in water or salt in water, the refractive index changes in step with how much of each component is present. Scientists have long known this to be true, and refractometers have a long history of use in brewing, sugar refining, analyzing blood and urine protein and many other industries where a quick measure of refractive index can lead to a good assessment of what is present.

Refractive index generally cannot reveal the identity of compounds in water, but when an aquarist knows roughly what material is there he can determine how much of it is there (within the refractive index’s detection capability). Changes in refractive index are not suitable for determining trace levels of ions (such as the purity of freshwater coming out of an RO/DI (reverse osmosis/deionization) purification system), but it can do a good job when significant amounts of a known material are present.

For example, refractive index cannot determine whether a salt in water is potassium sulfate, sodium chloride, magnesium nitrate or calcium bromide, but if you know which of these you have by some other means (such as the name on a chemical’s bottle), then you can determine how much is present in solution by measuring the refractive index, and then looking it up in a table that relates the refractive index to the concentration of that material.

Refractive Index and Salinity

Aquarists can use the effects that added salts have on the refractive index of a water solution to determine the salinity of reef aquarium water. As the salinity of seawater rises, the amount of salt added rises, so the refractive index rises. Figure 1 plots seawater’s refractive index vs. its salinity. Figure 2 shows a similar plot of seawater’s refractive index vs. specific gravity. These data are also summarized in Table 1. These sets of data demonstrate how aquarists can use refractive index to measure salinity and specific gravity, assuming they have a refractometer that can read in the appropriate refractive index range.

Figure 1. A plot of the relationship between the refractive index and the salinity of seawater.

 

[KrisReef]

This is a great question that I did not know the answer to! Had to google it so I would say #1.

The interweb got it wrong?