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This is exactly what I have meant and what I have meant with the "unexpected behavior of pH probes". When mixing different liquids with different pHs the pH meter shows ups and downs. I thought that such a spike must be such an event. Thank you, Randy! So this is not really a "bolus effect" but an artifact.If we are talking about the kind of spike in the graph below just after 8:00, it can only be a pH meter glitch (say, electrical interference), or the alk additive encountering the pH probe before it gets mixed in (which is consistent with the users description of the setup). Note that a sodium bicarbonate solution has a pH value in the mid 8's.
It is also possible that such a pH value for sodium bicarbonate solution may have misled some users to assume that if it has a pH higher than the tank, that it will necessarily raise pH. That is not true because bicarbonate is a significantly stronger acid in seawater than in a simple sodium bicarbonate solution.