Unbalanced to balanced dosing

Clownfishy

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For some time now, I have never managed to balance my dosing and have dosed unequal amounts. I could not track down why and just assumed some reefs run different to others. Well, I think I have found the issue so thought it would be useful to document that here just in case others are having the same issue as this may also be the cause. I was previously dosing -
Alk 42ml
Cal 28ml
Mineral Salt / Magnesium 28ml (magnesium was also 3 times the recommended strength)

For further infomration on the water chemistry and the reef aquarium itself, please see this thread.

Previous Alkalinity Additive
I was using Arm & Hammer Baking Soda for Alkalinity where I mixed 99g per 1 litre of RO/DO water. I have since learnt this is on the high side however, this in theory would make the solution stronger not weaker, yet as you can see from the above, I was having to add more Alkalinity than Calcium.

Previous Calcium Additive
I previously purchased 5kg of food unbranded Calcium Chloride and mixed 132g per 1 litre of RO/DO water. I suspect this was also over the amount required and as it was unbranded, I had no way of knowing.

New Additives
As my 5kg of Calcium was running out and as I have been using Aquaforest as part of my 3 part, I decided to purchase Aquaforest Calcium so I would be using their Calcium, Mineral Salt (Part 3) but stayed with Arm & Hammer Baking Soda. I kept with Baking Soda as it is cheap to make and gives me a much needed pH boost. I reached out to Randy to confirm how much of the Baking Soda I should use with the Aqua Forest products (see here) and this is where I learnt the quantities of my previous mixing had been wrong which could well have been the cause of my unbalanced dosing.

Balanced Again
Since mixing the quantities below, I now dose the same quantities of each component albeit higher quantities (58ml per day). Some of the increase is due to the coral growth I have observed over the last few months. I have also now reduced the Magnesium concentration down from 3 times the recommended quantity to 1.5 times but will see if this maintains levels or not.
AdditiveWater VolumeWeightAF Strong
Calcium Chloride1 Litre50g5ml Strong A
5ml Strong B
Baking Soda1 Litre80g5ml Strong C
Mineral Salt / Magnesium1 Litre25g
15g
5ml Strong K

A big shout out to @Randy Holmes-Farley for his continuous support to people like me where chemistry is not a strength! His DIY recipes have helped thousands of people and his advice is second to none.
 

gbroadbridge

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For some time now, I have never managed to balance my dosing and have dosed unequal amounts. I could not track down why and just assumed some reefs run different to others. Well, I think I have found the issue so thought it would be useful to document that here just in case others are having the same issue as this may also be the cause. I was previously dosing -
Alk 42ml
Cal 28ml
Mineral Salt / Magnesium 28ml (magnesium was also 3 times the recommended strength)

For further infomration on the water chemistry and the reef aquarium itself, please see this thread.

Previous Alkalinity Additive
I was using Arm & Hammer Baking Soda for Alkalinity where I mixed 99g per 1 litre of RO/DO water. I have since learnt this is on the high side however, this in theory would make the solution stronger not weaker, yet as you can see from the above, I was having to add more Alkalinity than Calcium.

Previous Calcium Additive
I previously purchased 5kg of food unbranded Calcium Chloride and mixed 132g per 1 litre of RO/DO water. I suspect this was also over the amount required and as it was unbranded, I had no way of knowing.

New Additives
As my 5kg of Calcium was running out and as I have been using Aquaforest as part of my 3 part, I decided to purchase Aquaforest Calcium so I would be using their Calcium, Mineral Salt (Part 3) but stayed with Arm & Hammer Baking Soda. I kept with Baking Soda as it is cheap to make and gives me a much needed pH boost. I reached out to Randy to confirm how much of the Baking Soda I should use with the Aqua Forest products (see here) and this is where I learnt the quantities of my previous mixing had been wrong which could well have been the cause of my unbalanced dosing.

Balanced Again
Since mixing the quantities below, I now dose the same quantities of each component albeit higher quantities (58ml per day). Some of the increase is due to the coral growth I have observed over the last few months. I have also now reduced the Magnesium concentration down from 3 times the recommended quantity to 1.5 times but will see if this maintains levels or not.
AdditiveWater VolumeWeightAF Strong
Calcium Chloride1 Litre50g5ml Strong A
5ml Strong B
Baking Soda1 Litre80g5ml Strong C
Mineral Salt / Magnesium1 Litre25g
15g
5ml Strong K

A big shout out to @Randy Holmes-Farley for his continuous support to people like me where chemistry is not a strength! His DIY recipes have helped thousands of people and his advice is second to none.

FWIW, Baking Soda does not give a pH boost, it actually lowers pH.
You need to bake the Baking Soda to make Washing Soda to give a pH boost.

If you were to do that you would use 50g Washing Soda (Sodium Carbonate) instead of 80g Baking Soda (Sodium Bicarbonate).

Which is the recipe I use (but I mix at twice the concentration) ...
 
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Clownfishy

Clownfishy

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FWIW, Baking Soda does not give a pH boost, it actually lowers pH.
You need to bake the Baking Soda to make Washing Soda to give a pH boost.

If you were to do that you would use 50g Washing Soda (Sodium Carbonate) instead of 80g Baking Soda (Sodium Bicarbonate).

Which is the recipe I use (but I mix at twice the concentration) ...
Apologies, I forgot to mention, I do bake it first so may have misspoke. Sorry for the dumb chemistry question but why does this then reduce the amount and are there any issues mixing more? What is weird is that by mixing at 80g has still allowed me to balance my dosing.

Many thanks for the info.
 

Randy Holmes-Farley

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