I don’t use polylab I personally believe it’s just a management tool it won’t eradicate ich or velvet.
This
And, I do believe your fish has both a very heavy ich infestation, and definitely black ich. I can see the black spots clearly in the first set of photos.
I don’t think it looks like velvet personally, but without seeing it in person it’s hard to say with certainty... some tangs can get so covered in ich that it actually looks like velvet